氧化物热电材料及其研究进展(2)

2019-03-29 16:57

值大于2时开发出的热电设备才能与传统设备相抗衡。

目前,研究人员在氧化物热电材料研究中遇到的问题主要有两个:一是材料的电导率仍偏低,而热导率仍偏高,很难同时兼顾材料的电输运和热输运性能。二是对一部分氧化物热电材料的电热输运机理尚不清楚。

3.2 解决方案与展望

在当前研究状况下,继续寻找Seebeck系数和电导率更高,而热导率更低的新型氧化物热电材料。可以探索和应用新的合成工艺和制备方法,使用不同的制备方法获得的热电材料,其热电性能往往差异很大。或者探索使用低维热电材料,利用其超周期性和量子限制效应,降低材料热导率的同时不会降低其电导率。

氧化物热电材料的优势是其它热电材料所无法比拟的,是一种很有发展前途的热电材料。近几年,研究人员合成的氧化物热电材料其热电性能正一点点提高,在不远的将来,氧化物热电材料能够从实验室研究走向实际应用,以获得清洁安全的新能源,提高现有能源的使用效率,减少对煤、石油、天然气等传统能源的依赖,有效的保护大气环境。

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