Cl4.Cl2FeOHH2OOH-NO2NO2NaOH浓HNO3浓H2SO4ClNO2+Cl浓HNO3浓H2SO4NO2ClNO2ONaNO2NO2ClCH2COONaNO2OCH2COONaNO2NO2
5.CH3CH2BrMg无水乙醚CH3CH2MgBrCHOCCH33CH3CCH2CH3CH3OH浓H2SO4浓H2SO4
6.CH3C=CH2CH3CH3ClCH2CH3Cl2hvHCNCH3CH2BrAlCl3KOH-C2H5OHOCH3COCH3COCCH3ClC=CH2H3O+CNOCOCHC=CH2COOH
NH27.NH2NHCCH3浓HNO3浓H2SO4NHCCH3H2O/OH-NO2Br2（过量）FeNO2NO28.BrFeNH2BrBrNO2NO2HNO2H3PO2BrNO2CH2CH2OBrNO2H2OCH2CH2OHNO2BrMgTHF
MgBr
CH39.浓HNO3浓H2SO4NO2CH3Fe-HClNH2CH3OCH3COCH3COCH3NHCOCH3 35
CH3浓HNO3浓H2SO4H2O/OH-NO2NHCOCH3CH3HNO2NO2NH2CH3H3PO2NO2N2+CH3NO2
10.CH3CH=CH2CH3CH2CH2BrPCl3HBrH2O2H2OOH-CH3CH2CH2BrNH3[O]CH3CH2CH2NH2CH3CH2COOHOCH3CH2CNHCH2CH2CH3
CHOCCH33CH3CH2MgBrCH3CH2CH2OHOCH3CH2CH2NH2CH3CH2CClHBrCH3CH2Br浓H2SO4Mg无水乙醚11.CH3CH2OHH2OCH3CCH2CH3CH3OHCH3冷稀KMnO4C=CH2CH3CH3CH3CH3CHCCH3OHOH
CH2CH212.CCOOOOPCl3CH2CH2CH2CClCOCH2CH2COOHZn-Hg浓HClCH2CH2CH2COOHAlCl3AlCl3OZn-Hg浓HClOCH3CClAlCl3
13.CH3CHCH3BrCOCH3CH3MgBrH2OCH3CCH3OHAlCl314.+CHOH2-NiCH2OH
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15.CH3COCHCOOC2H5CH3COCHCOOC2H5CH2CH=CH2NaOC2H5稀OH-CH3COCHCOOC2H5-CH2=CHCH2ClCH3COCH2CH2CH=CH2
CH3COCHCOO-CH2CH=CH2稀H+,-CO2八、选择题
1.d; 2.c; 3.a; 4.b; 5.a; 6.d; 7.a; 8.d; 9.d; 10.c;
11.a; 12.d; 13.c; 14.a; 15.d; 16.b; 17.d; 18.d; 19.a; 20.d; 21.b; 22.b; 23.d; 24.d; 25.b; 26.c; 27.d; 28.b; 29.c; 30.d; 31.c; 32.d; 33.d; 34.c; 35.d; 36.d; 37.c; 38.a; 39.d; 40.a; 41.a; 42.c; 43.d; 44.b; 45.b; 46.d; 47.a; 48.c; 49.a; 50.c; 51.d; 52.c; 53.a; 54.a; 55.d; 56.a; 57.a; 58.c; 59.a; 60.a; 61.a; 62.b; 63.a; 64.b; 65.d; 66.c; 67.b; 68.a; 69.d; 70.a; 71.b; 72.a; 73.b; 74.b; 75.c; 76.c; 77.c; 78.b; 79.c; 80.a
九、推测下列结构式
O1.CCH3OH4.CH3;ONa2.HOOCCH3OC2H5OC2H5H3.HOOCCOOCH3CH3
CH3;CH3;COOH
OCH3CHCO5.CH2CO(A)
;CH3CHCOOH;CH2COOC2H5(B)CH3CHCOOC2H5;CH2COOH(C)CH3CHCOOC2H5CH2COOC2H5(D)OO6.CH3CH2CCH2COCH(CH3)2
7.CH3CCOOHCHCOOH;(A)CH3CHCOOHCH2COOH;(B)OCH3CCOCHCO(C)
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8.A.H2NC.HOCOOHOCNH2B.H2ND.CH3C2H5CHCOOHC2H5(B)
CHO11.CHCH3OH
OOCHNO29.CH2=CHCHCOOHC2H5(A)OHCH3CH3CCH10.CH3CH3
;12.13.14.15.18.19.21.CH3CH3OCH3CH=CCH2NH2;CH3CH2CHCH2NH2;CH3CCH2NH2(A)(C)(B)
OCH2CH2CH2CH2C;CH2CH2CH2CH2COOH;HOOCCH2CH2CH2COOHOOH(B)(C)(A)
CH3CCH2CH2CH=CH2或CH2=CCH2CH2CHOOCH3 OHOOCOOH16.CH3CCHCHO17.HOCH2CH2COCH=CH2CH3
OCH2CH2OHCHOCHOCH2;;CH2OH(A)(B)(C) OCH3C=CHCH2CH2CHCH2CHO20.CH3CH2CCH(CH3)2CH3CH3OOHCH3OH22.CHCCHCOOCH32;CH3COO(A)23.(1)CH3CH=CHCHO;(C)CH3CHOC=CHHCH3HC=CCHO HCHOHBrBrHCH3
CHOBr(2)顺式：HBrHCH3 38
(3)反式：CHOHBrHBrCH3CHOBrHBrHCH3
24.CH3CHCH(CH3)2OH(A)CH2;CH3CCH(CH3)2O(B)CH3HC Cl;CH3CH=C(C)CH3CH3
CH3Cl或CH25.A:CClB:O26.CH3 C O CH CH2
OH27.CH2COOHNCH3CH3(A)(B)
OC2H5CCOOHCCHO29.CH3;COOH;CCH3;O(C)(B)(A)（D）
30.CH3CH=CCH=CHCH(CH3)231.(CH3)2CHCH2CCH;CH3CH2CH=CHCH=CH2(A)(B)CHNCH3CH3CH328.OCH2CCH3;
3CH3CH3C2H5(A)CH=CH2CCH3O(B)33.CH3(B)32.CH3CH=CCCHC2H534.CH=CH2CCH(A);(B)CH=CH2COOH(C)36.H3CCH3
CHOCOOH（D）
35.CH2=CCH2CCH;CH3(A)37.C2H5CHCCHCH3(A);C2H5CHC2H5CH3(B)38.(A)CH3
CH3;(B)
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