方法2:
A = (Ls /GB)/m = 1.244/0.526 = 2.365
NOG = A/(A-1)×ln[(1-1/A)(Y1-mX2)/(Y2-mX2)+1/A] = 2.365/1.365×ln[(1-1/2.365)(0.026/0.0026) +1/2.365] = 3.16 ∴ KYa= 37.42 kmol.m-3.h-1?
4、在常压逆流操作的填料塔内,用纯溶剂S 吸收混合气体中的可溶组分A 。入塔气体中A 的摩尔分率为0.03,要求吸收率为95%。 已知操作条件下的解吸因数为0.8 ,物系服从亨利定律,与入塔气体成平衡的液相浓度为0.03(摩尔分率)。 试计算: (1) 操作液气比为最小液气比的倍数; (2) 出塔液体的浓度; (3) 完成上述分离任务所需的气相总传质单元数NOG。
解:
① y1 = 0.03 , x1e = 0.03 ,所以m = 1 (L/G)min = (y1-y2)/(y1/m) = mη = 0.95 S = m/(L/G), L/G = m/S = 1/0.8 = 1.25 ∴ (L/G)/(L/G)min = 1.25/0.95 = 1.316
② x1 = (y1-y2)/(L/G) = (0.03-0.03(1-0.95))/1.25 = 0.0228 ③ NOG = 1/(1-S)ln[(1-S)Y1/Y2+S] = 7.843。
5、常压下,用煤油从苯蒸汽与空气混合物中吸收苯,吸收率为99%。混合气量为53kmol.h-1。入塔气中含苯2%(比摩尔以下同),入塔煤油中含苯0.02%。溶剂用量为最小用量的1.5倍。在操作温度50℃下,相平衡关系为y = 0.36x,总传质系数Kya = 0.015kmol.m-3.s-1。塔径为1.1米。试求所需填料层高度。
解:
y1 = 0.02,y2 = 0.02×1%=0.0002
x1e = y1e/m = 0.02/0.36 = 0.0556,x2 = 0.0002 (L/G)min = (y1-y2)/(x1e-x2)
= (0.02-0.0002)/(0.0556-0.0002) = 0.3574 L/G = 1.5(L/G)min = 1.5×0.3574 = 0.536 x1 = x2 + (y1- y2)/(L/G)
=0.0002+(0.02-0.0002)/0.536 = 0.0371 Δy1 = y1 –mx1 = 0.02-0.36×0.0371 = 0.00664 Δy2 = y2 –mx2 = 0.0002-0.36×0.0002 = 0.000128 Δym = (0.00664-0.000128)/ln(0.00664/0.000128) = 0.00165
NOG = (y1-y2)/Δym = (0.02-0.0002)/0.00165 = 12
HOG = G/(Kya) = 53/3600/(π/4×1.12 )/0.015 = 1.033 m Z = HOG×NOG = 1.033×12 = 12.4 m
6、有一逆流填料吸收塔, 塔径为0.5m,用纯溶剂吸收混合气中的溶质。入塔气体量为100kmol.h-1,溶质浓度为0.01(摩尔分率),回收率要求达到90%,液气比为1.5 ,平衡关系y = x。试求:
(1) 液体出塔浓度;(2) 测得气相总体积传质系数Kya = 0.10 kmol.m-3.s-1,问该塔填料层高度为 多少?提示:NOG = 1/(1-S)ln[(1-S)(y1-mx2)/(y2-mx2)+S]
解:
① y1 = 0.01
y2 = y1(1-η) = 0.01(1-0.9) = 0.001 L/G=(y1-y2)/x1,
x1 = (y1-y2)/(L/G) = (0.01-0.001)/1.5 = 0.006
② HOG = G/Kya = (100/(0.785×0.52×3600))/0.1=1.415 m NOG = 1/(1-S)ln[(1-S) y1/ y2+S] S = m/(L/G) = 1/1.5 = 0.667 NOG = 4.16
Z = HOG×NOG = 1.415×4.16 = 5.88 m。
11
7、用清水吸收氨-空气混合气中的氨。混合气进塔时氨的浓度y1 = 0.01(摩尔分率),吸收率90%,气-液平衡关系y = 0.9x。试求:(1)溶液最大出口浓度;(2)最小液气比;(3)取吸收剂用量为最小吸收剂用量的2倍时,气相总传质单元数为多少?(4)气相总传质单元高度为0.5m时,填料层高为几米? 解: 已知
y1 = 0.01,η=90%,y2 = y1(1-η) = 0.01(1-0.9) = 0.001 x2 = 0,x1 = y1/0.9 = 0.01/0.9 = 0.0111 (L/G)min = (y1-y2)/(x1e-x2)
= (0.01-0.001)/(0.01/0.9)= 0.811 L/G = 2 (L/G)min = 2×0.811 = 1.62
x1 = (y1-y2)/(L/G)+x2 = (0.01-0.001)/1.62 = 0.00556
y1e = 0.9×0.00556=0.005
Δym =((0.01-0.005)-(0.001-0))/ln(0.01-0.005)/0.001 = 0.0025
NOG = (y1-y2)/Δym = (0.01-0.001)/0.0025 = 3.6 Z = 0.5×3.6 = 1.8m
8、在逆流操作的吸收塔内,用清水吸收氨-空气混合气中的氨,混合气进塔时氨的浓度y1 = 0.01(摩尔分率) ,吸收率90%,操作压力为760 mmHg,溶液为稀溶液,系统平衡关系服从拉乌尔定律,操作温度下,氨在水溶液中的饱和蒸汽压力为684 mmHg试求: (1)溶液最大出口浓度;(2)最小单位吸收剂用量;(3)当吸收剂用量为最小用量的2倍时,气相总传质单元数为多少?(4)气相总传质单元高度为0.5m时,填料层高为多少米? 解:
系统服从拉乌尔定律 (1) y = (P°/P)x = 685/760X = 0.9X x1e = y1/m = 0.01/0.9 = 0.011
(2) (L /G )min = (y1-y2)/x1e = (y1-y2)/(y1/m) = mη = 0.9×0.9=0.81 (3) (L /G ) = 2(Ls /G )min = 2×0.81 = 1.62
S = mG/L =0.9/1.62=0.556 y1/ y2 = 1/(1-η) = 10
NOG = 1/(1-S)×ln[(1-S) y1/ y2+S] = 1/(1-0.556)×ln[(1-0.556)×10+0.556] = 3.62 (4) Z = HOG×NOG = 0.5 ×3.62 = 1.81 m 9、在直径为0.8m的填料塔中,用1200kg·.h-1的清水吸收空气和SO2混合气中的SO2,混合气量为1000m3(标准)·h-1,混合气含SO21.3%(体积),要求回收率99.5%。操作条件为20℃、1atm,平衡关系为y = 0.75x,总体积传质系数Kya = 0.05kmol·m-3·s-1,求液体出口浓度和填料层高度。 解:
已知:D = 0.8m Ls =1200kg.h-1,G = 1000Nm3·h-1? y1 = 0.013,φ = 0.995,x2 = 0,y = 0.75x Kya = 0.05kmol·m-3·s-1, Ls = 1200/(3600×18)=0.0185 kmol/s G = 1000/(22.4×3600)=0.0124 kmol/s
∵为低浓度吸收 ∴ (L/G) = 0.0185/0.0124 = 1.49 y2 = y1(1-φ) = 0.013(1-0.995) = 0.000065
x1 = (G/L)(y1-y2)+x2 = (0.013-0.000065)/1.49 = 0.00 868 ∵ Z = HOG×NOG,而NOG = (y1-y2)/Δym
Δy1 = y1-y2e = 0.013-0.75×0.00868 = 0.006490 Δy2 = y2-y2e = 0.000065-0 = 0.000065 Δym = (Δy1-Δy2)/ln(Δy1/Δy2)
12
= (0.006490-0.000065)/ln(0.006490/0.000065) = 0.001396
∴NOG = (0.013-0.000065)/0.001396 = 9.266 HOG = G/(KyaA)
= 0.0124/(0.785×0.8×0.8×0.05)= 0.494(m) ∴Z = 9.266×0.494 = 4.58m
10、某厂准备采用一个填料吸收塔用清水逆流吸收含有10%(体积%)的SO2的混合气体。已知塔内的操作压力 102.63kN·m2 和温度 25℃。要求处理的混合气体量为1000(标准)m3·h-1,实际吸收剂单位耗用量比最小吸收剂单位耗用量大50%,吸收率要达到98%,塔内气体的实际空塔速度为0.5m·s-1。试求: (1) 吸收用水量为多少m3·h-1? (2) 吸收塔直径为多少m? (3) 若想再提高吸收率,你认为可采用什么措施?(附:气液平衡方程:Y = 40X,M = 64) 解:
(1)LS = GB(Y1-Y2)/(X1-X2)
Y1 = 10/90 = 0.111;Y2 = 0.111(1-0.98) = 0.0222 又∵LS = 1.5 LSmin
而:X1 = Y1/1.5m = 0.111/1.5×40 = 0.00185 GB = 1000(1-0.1)/22.4 = 40.18kmol·h-1
-1
代入上式得:LS = 1928.64 kmol·h
2
(2) D = (4G混/πu)??
而G混 = 1000×(101.3/102.63)×(298/273)=1077.4 m3·h-1?
u = 0.5m·s-1,代入上式得:
D = 0.873m,圆整为0.9m。
(3)对于一个操作塔言,欲提高φ,增大液气比,这样可使吸收推动力增大,则φ↑。此外,液气比增大,喷淋密度增大,有利于填料充分润湿!注意:液气比增大,但液气比过大,会造成液泛现象。
11、一填料塔用清水逆流吸收混合气中的有害组分A。已知操作条件下气相总传质单元高度为1.5m,进塔混合气组成为0.04(A的摩尔分率,下同),出塔尾气组成为0.0053,出塔水溶液浓度为0.0128,操作条件下平衡关系为Y=2.5X。试求:(1)液气比为最小液气比的多少倍?(2)所需填料层高度? 解:(1)液气比为最小液气比的多少倍?
0.040.0053?0.0417 Y2??0.00533
1?0.041?0.00530.00128?0.01297 X1?1?0.00128 Y1? L/V?Y1?Y20.0417?0.00533??2.804
X1?X20.01297?0Y1?Y2Y1?Y20.0417?0.00533???2.18 ?Y1/m0.0417/2.5X1?X2 (L/V)min? 则
(L/V)(L/V)min?2.804?1.286
2.18
(2)所需填料层高度?
Z?HOG?NOG S?mV/L?2.5/2.804?0.892
13
NOG? ?Y?mX21ln[(1?S)1?S]1?SY2?mX210.0417?0ln[(1?0.892)?0.892]
1?0.8920.00533?0?5.11故 Z?HOG?NOG?1.5?5.11?7.67m
14