31 加［成］聚［合］ 自由基聚合，
addition polymerization free radical polymerization, radical polymerization
controlled radical polymerization，CRP
32
游离基聚合 (曾用名) 控制自由基聚合，
33
可控自由基聚合
34 35 36
活性自由基聚合 原子转移自由基聚合
living radical polymerization
atom transfer radical polymerization，ATRP 反向原子转移自由基聚合 reverse atom transfer radical polymerization， RATRP 可逆加成断裂链转移
reversible addition fragmentation chain transfer，RAFT
37
38 39 40 41 42
氮氧[自由基]调控聚合 稳定自由基聚合 自由基异构化聚合 自由基开环聚合 氧化还原聚合 无活性端聚合，
nitroxide mediated polymerization stable free radical polymerization，FRP free radical isomerization polymerization radical ring opening polymerization redox polymerization dead end polymerization
43
死端聚合 (曾用名)
44 45 46 47 48 49 50 51 52
光［致］聚合 光引发聚合 光敏聚合 四中心聚合 电荷转移聚合 辐射引发聚合 热聚合 电解聚合 等离子体聚合
photo polymerization light initiated polymerization photosensitized polymerization four center polymerization charge transfer polymerization radiation initiated polymerization thermal polymerization electrolytic polymerization plasma polymerization
53 易位聚合 54 开环易位聚合
55 精密聚合 56 环化聚合 57 拓扑化学聚合 58 平衡聚合 59 离子［型］聚合 60 辐射离子聚合 61
离子对聚合 正离子聚合，
62
阳离子聚合
63 碳正离子聚合
64 假正离子聚合 65 假正离子活［性］聚合 66
活性正离子聚合 负离子聚合，
67
阴离子聚合
68 碳负离子聚合 69 活性负离子聚合 70 负离子环化聚合 71 负离子电化学聚合 72 负离子异构化聚合 73 烯丙基聚合 74 活［性］聚合 75 两性离子聚合 76
齐格勒-纳塔聚合
metathesis polymerization ring opening metathesis polymerization， ROMP
precision polymerization cyclopolymerization topochemical polymerization equilibrium polymerization ionic polymerization radiation ion polymerization ion pair polymerization cationic polymerization
carbenium ion polymerization,carbocationic polymerization
pseudo cationic polymerization pseudo cationic living polymerization living cationic polymerization anionic polymerization
carbanionic polymerization living anionic polymerization anionic cyclopolymerization
anionic electrochemical polymerization anionic isomerization polymerization allylic polymerization living polymerization zwitterion polymerization Ziegler Natta polymerization
77 配位聚合 78 配位离子聚合 79 配位负离子聚合 80 配位正离子聚合 81
插入聚合 定向聚合，
82
立构规整聚合
83 有规立构聚合 84 全同立构聚合 85 不对称诱导聚合 86 不对称选择性聚合 87 不对称立体选择性聚合 88 对映［体］不对称聚合 89 对映［体］对称聚合 90 异构化聚合 91 氢转移聚合 92 基团转移聚合 93 消除聚合 94 模板聚合
95 插层聚合 96 无催化聚合 97 开环聚合 98 活性开环聚合 99 不死的聚合 100 酶聚合作用 101
聚加成反应，
coordination polymerization coordinated ionic polymerization coordinated anionic polymerization coordinated cationic polymerization insertion polymerization
stereoregular polymerization, stereospecific polymerization tactic polymerization isospecific polymerization
asymmetric induction polymerization asymmetric selective polymerization asymmetric stereoselective polymerization enantioasymmetric polymerization enantiosymmetric polymerization isomerization polymerization hydrogen transfer polymerization group transfer polymerization，GTP elimination polymerization matrix
polymerization,template polymerization
intercalation polymerization uncatalyzed polymerization ring opening polymerization living ring opening polymerization immortal polymerization enzymatic polymerization polyaddition
逐步加成聚合 (曾用名)
102 偶联聚合 103 序列聚合
104 闪发聚合，俗称暴聚 105 氧化聚合 106 氧化偶联聚合 107
逐步［增长］聚合 缩聚反应
108
酯交换型聚合
109
110 自催化缩聚 111 均相聚合 112 非均相聚合 113 相转化聚合 114 本体聚合 115
固相聚合 气相聚合
116
117 吸附聚合 118 溶液聚合 119 沉淀聚合 120 淤浆聚合 121 悬浮聚合 122 反相悬浮聚合 123 珠状聚合 124
分散聚合
coupling polymerization sequential polymerization flash polymerization oxidative polymerization oxidative coupling polymerization step growth polymerization condensation polymerization，
polycondensation
transesterification type polymerization,
ester exchange polycondensation
autocatalytic polycondensation homogeneous polymerization heterogeneous polymerization phase inversion polymerization
bulk polymerization, mass polymerization solid phase polymerization gaseous polymerization,
gas phase polymerization
adsorption polymerization solution polymerization precipitation polymerization slurry polymerization suspension polymerization
reversed phase suspension polymerization bead polymerization, pearl polymerization dispersion polymerization
125 反相分散聚合 126 种子聚合 127 乳液聚合 128 无乳化剂乳液聚合 129 反相乳液聚合 130 微乳液聚合 131 连续聚合 132 半连续聚合 133 分批聚合，间歇聚合134 原位聚合 135 均相缩聚 136 活化缩聚 137 熔融缩聚 138 固相缩聚 139 体型缩聚 140 界面聚合 141 界面缩聚 142 环加成聚合 143 环烯聚合 144 环硅氧烷聚合 145 引发剂 146 引发剂活性 147 聚合催化剂 148 自由基引发剂 149 偶氮［类］引发剂 150 2,2′偶氮二异丁腈 151
过氧化苯甲酰
inverse dispersion polymerization seeding polymerization emulsion polymerization
emulsifier free emulsion polymerization inverse emulsion polymerization micro emulsion polymerization continuous polymerization semicontinuous polymerization batch polymerization in situ polymerization homopolycondensation activated polycondensation melt phase polycondensation solid phase polycondensation three dimensional polycondensation interfacial polymerization interfacial polycondensation cycloaddition polymerization cycloalkene polymerization cyclosiloxane polymerization initiator
activity of initiator polymerization catalyst radical initiator azo type initiator
2,2'- azobisisobutyronitrile, AIBN benzoyl peroxide, BPO