图10
图11
图12给出了屏蔽效果作为粘土含量的函数。由图12可知,粘土含量从5%增加到10%时,紫外线透射率显著减小,然而透明度却很高(图11)。UV-A 和UV-B 也会减少,UV-B减小的相对较少。
使用DMSO夹层高岭石对保护透明性有利,甚至有良好的阻隔紫外线能力。
图12
6.结论
在这项研究中,对高岭石含量对木薯淀粉薄膜性能的影响进行了研究。使用DMSO夹层高岭石对粘土的扩散和分布是有利的,这会增强粘土含量对薄膜性能的影响。动态机械热分析(DMTA)显示,当粘土含量达到10%时,玻璃化的转变温度(Tg)会降低。通过减少聚合物链之间的相互作用,促进它们的流动性,粘土有增塑剂的作用。使用DMSO夹层高岭石会使Tg变得更低,这是由于它对链-链相互作用的强干扰导致的。从差示扫描量热法(DSC)可知,淀粉基体的热解温度会
随粘土含量增加而增加,粘土含量上限为10%。
此外,薄膜在100%和50%的相对湿度下水摄入量(WU)的结果表明,在低相对湿度下,粘土含量对WU起到阻碍作用,然而高相对湿度下,对聚合物薄膜的WU起到促进作用。
添加夹层高岭石的薄膜的透明性降低值相对较少,当粘土含量在2%到6%时,具有显著紫外光阻隔效果,同时会保持透明度。
参考文献:
Avella, M., De Vlieger, J. J., Errico, M. E., Fischer, S., Vacca, P., & Volpe, M. G. (2005).
Biodegradable starch/clay nanocomposite films for food packaging applications. Food Chemistry, 93, 467–474.
Avérous, L., & Halley, P. J. (2009). Plasticized starch based-biocomposites. Biofuels,
Bioproducts and Biorefining, 3, 329–343.
Carvalho, A. J. F., Curvelo, A. A. S., & Agnelli, J. A. M. (2001). A first insight on com-
posites of thermoplastic starch and kaolin. Carbohydrate Polymers, 45, 189–194. Chen, B., & Evans, J. R. G. (2005). Thermoplastic starch–clay nanocomposites and
their characteristics. Carbohydrate Polymers, 61, 455–463.
Famá, L., Flores, S. K., Gerschenson, L., & Goyanes, S. (2006). Physical characteriza-
tion of cassava starch biofilms with special reference to dynamic mechanical properties at low temperatures. Carbohydrate Polymers, 66, 8–15. Forssell, P. M., Mikkila, J. M., Moates, G. K., & Parker, R. (1997). Phase and glass
transitions behaviour of concentrated barley starch–glycerol mixtures, a model for thermoplastic starch. Carbohydrate Polymers, 34, 275–282.
Gardolinski, J. E., Carrera, L. C. M., & Wypych, F. (2000). Layered polymer–kaolinite
nanocomposites. Journal of Materials Science, 35, 3113–3119.
Godbillot, L., Dole, P., Joly, C., Roge, B., & Mathlouthi, M. (2006). Analysis of water
binding in starch plasticized films. Food Chemistry, 96, 380–386. He, S., Yaszemski, M. J., Yasko, A. W., Engel, W. P., & Mikos, A. G. (2000).
Injectable biodegradable polymer composites based on poly(propylene fumu- rate) crosslinked with poly(ethylene glycol)-dimethacrylate. Biomaterials, 21,
2389–2394.
Huang, M.-F., Yu, J.-G., & Ma, X.-F. (2004). Studies on the properties of
montmorillonite-reinforced thermoplastic starch composites. Polymers, 45, 7017–7023.
Laohakunjit, N., & Noomhorm, A. (2004). Effect of plasticizers on mechanical and
barrier properties of rice starch film. Starch/St?rke, 56, 348–356.
Lourdin, D., Coignard, L., Bizot, H., & Colonna, P. (1997). Influence of equilibrium
relative humidity and plasticizer concentration on the water content and glass transition of starch materials. Polymer, 38(21), 5401–5406.
McGlashan, S. A., & Halley, P. J. (2003). Preparation and characterization of
biodegradable starch-based nanocomposite materials. Polymer International, 52, 1767–1773.
Njoya, A., Nkoumbou, C., Grosbois, C., Njopwouo, D., Njoya, D., Courtin-Nomade, A.,
et al. (2006). Genesis of Mayouom kaolin deposit (western Cameroon). Applied Clay Science, 32, 125–140.
Okamoto, M. (2005). Biodegradable polymer/layered silicate nanocomposites: A
review. In S. Mallapragada, & B. Narasimhan (Eds.), Handbook of biodegradable polymeric materials and their applications. American Scientific Publishers, pp. 1–45.
Olejnik, V. S., Aylmore, L. A. G., Posner, A. M., & Quirk, J. P. (1968). Infrared spectra of
kaolin mineral–dimethyl sulfoxide complexes. The Journal of Physical Chemistry, 72(1), 241–249.
Park, H., Li, X., Jin, C., Park, C., Cho, W., & Ha, C. (2002). Preparation and properties of
biodegradable thermoplastic starch/clay hybrids. Macromolecular Materials and Engineering, 287, 553–558.
Park, H., Lee, W., Park, C., Cho, W., & Ha, C. (2003). Environmentally friendly polymer
hybrids. Part 1. Mechanical, thermal and barrier properties of thermoplastic starch/clay nanocomposites. Journal of Materials Science, 38, 909–915. Park, H., Misra, M., Drzal, L. T., & Mohanty, A. K. (2004). Green nanocomposites
from cellulose acetate bioplastic and clay: Effect of eco-friendly triethyl citrate
plasticizer. Biomacromolecules, 5, 2281–2288.
Parra, D. F., Tadini, C. C., Ponce, P., & Lugao, A. B. (2004). Mechanical and water
vapor transmission in some blends of cassava starch edible films. Carbohydrate Polymers, 58, 475–481.
Pérez, C. J., Alvarez, V. A., Mondragón, I., & Vázquez, A. (2007). Mechanical proper-
ties of layered silicate/starch polycaprolactone blend nanocomposites. Polymer International, 56, 686–693.
Ray, S. S., & Bousmina, M. (2005). Biodegradable polymers and their layered sili-
cate nanocomposites: In greening the 21st century materials world. Progress in Materials Science, 50, 962–1079.
Róz, A. L. D., Carvalho, A. J. F., Gandini, A., & Curvelo, A. A. S. (2006). The effect of
plasticizers on thermoplastic starch compositions obtained by melt processing. Carbohydrate Polymers, 63, 417–424.
Sanchez-Garcia, M. D., Hilliou, L., & Lagaron, J. M. (2010). Nanobiocomposites of car-
rageenan, zein, and mica of interest in food packaging and coating applications. Journal of Agricultural and Food Chemistry, 58(11), 6884–6894. Sorrentino, A., Gorrasi, G., & Vittoria, V. (2007). Potential perspectives of bio-
nanocomposites for food packaging applications. Trends in Food Science and Technology, 18, 84–95.
Talja, R. A., Yrjo Hélen, H., Roos, Y. H., & Jouppila, K. (2007). Effect of various polyols
and polyol contents on physical and mechanical properties of potato starch- based films. Carbohydrate Polymers, 67, 288–295.
Wilhelm, H. M., Sierakowski, M. R., Souza, G. P., & Wypych, F. (2003a).
Starch films reinforced with mineral clay. Carbohydrate Polymers, 52, 101–110.
Wilhelm, H. M., Sierakowski, M. R., Souza, G. P., & Wypych, F. (2003b). The influ-
enced of layered compounds on the properties of starch/layered compounds composites. Polymer International, 52, 1035–1044.
Yu, L., Dean, K., & Li, L. (2006). Polymer blends and composites from renewable
resources. Progress in Polymer Sciences, 31, 576–602.
Zeppa, C., Gouanve, F., & Espuche, E. (2009). Effect of a plasticizer on the
structure of biodegradable starch/clay nanocomposites: Thermal, water- sorption and oxygen-barrier properties. Journal of Applied Polymer Science, 112, 2044–2056.