?H0f,298,O2(g)?0
Qp??H???V?Hi0f.m.i?产物???V?Hj0f.m.i?反应物?2?(?393.51)?4?(?285.83)?2?(?238.7)?0??1452.94kJ/mol解:气相苯乙烯燃烧反应式为:
19.试用气相苯乙烯(C6H5C2H3)的标准燃烧热求它的标准生成热。
C8H8(g)?10O2(g)?8CO2(g)?4H2O(l)
查表得:?H0.51kJ/mol f,298,CO2(g)??393 ?H0.83kJ/mol f,298,H2O(l)??285 ?H0.46kJ/mol f,298,C6H5C2H3(g)??147 ?H0f,298,O2(g)?0
Qp??H???V?Hi0f.m.i??产物??V?Hj0f.m.i?反应物?8?(?393.51)?4?(?285.83)?(?147.46)?0??4143.94kJ/mol量。
20.已知木材的组成为:C-43%、H-7%、O-41%、N-2%、W-7%.求5公斤木材在25℃下燃烧的发热
QH?4.18?[81C?300H?26(O?S)]解:
?4.18??81?43?300?7?26?43??18664kJ/kg
QL?QH?6?(9H?W)?4.18?18664?6?(9?7?7)?4.18?16908kJ/kg
5kg木材燃烧的高热值为18664?5?93320kJ;低热值为16908?5?84540kJ
21.已知煤气的成份(见计算题12所列),试求4m3的该种煤气在25℃下燃烧的发热量。
解:查表得该煤气中各可燃组分的标准燃烧热分别为:
?Hc0,298,CO(g)?283.0kJ/mol?Hc0,298,H2(g)?285.83kJ/mol?Hc0,298,C2H4(g)?1411.0kJ/mol ?Hc0,298,CH4(g)?890.31kJ/mol?Hc0,298,C3H6(g)?2049kJ/mol该种煤气的标准燃烧热为
?Hc0,298?1411?0.48?285.83?0.372?890.31?0.267?2049?0.013?283?0.046?1034.71kJ/mol