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环境科学33卷
污染,但是沉积物质量基准法测算结果显示该区域的潜在生态毒性总体较低.造成这种差异主要原因是因为不同种类PAHs的潜在生态毒性效应差别.容桂街道PAHs以低环化合物为主,特别是2环和3环化合物含量在大多监控位点均占
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MarinePollution
Σ
PAHs的
75%以上.而2~3环类低环PAHs的生态毒性浓度效应低值和中值的浓度大大高于4环以上的PAHs效应值,因此出现了
Σ
PAHs含量较高,但是总体
潜在生态风险相对较低的现象.但由于质量基准法严重依赖于生物效应数据库,该效应结果还需要更多试验生物种类增加和评估方法的完善.3
结论
(1)佛山市顺德区容桂街道内河涌沉积物中,16种优先控制PAHs检出率达100%,其中12种PAHs在所有位点均检出.
Σ
PAHs含量范围为
343.5~2099μg·kg-1,·kg-1,均值为1215.9μg
PAHs总量污染属于重度污染.其中2~3环>4环>5~6环.包含居民区和制造业集中区各监测点
Σ
PAHs含量分布显示,该地区PAHs污染和电器
制造业存在没有直接相关性.
(2)监测区域PAHs主要污染源来自石油、生物质以及木柴燃烧等活动.垂直尺度沉积物比较结果显示,其燃烧类型具有从生物质向石油燃烧变化趋势,该变化和本地区快速的工业化发展有关.
(3)河涌沉积物总量污染和污染因子指标共同显示该地区PAHs污染严重,由于PAHs组分以低环为主,质量基准法判定其潜在生物毒性风险评价总S3和S7等位点仍具有较高的潜在生体不高,但S2、态风险.
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