禁用偶氮染料释放芳香胺欧盟测试方法,替代原-1&-2方法。
BS EN 14362-1:2012
EN 14362-1:2012 (E)
Table 1 — Aromatic amines proscribed under Regulation REACH 1907/2006/Annex XVII
No.
CAS number
Index number
EC number
Substances
1 92-67-1 612-072-00-6 202-177-1 biphenyl-4-ylamine
4-aminobiphenyl xenylamine 2 92-87-5 612-042-00-2 202-199-1 benzidine
3 95-69-2 612-196-00-0 202-441-6 4-chloro-o-toluidine 4 91-59-8 612-022-00-3 202-080-4 2-naphthylamine 5a
97-56-3 611-006-00-3 202-591-2 o-aminoazotoluene
4-amino-2',3-dimethylazobenzene 4-o-tolylazo-o-toluidine 6a
99-55-8 612-210-00-5 202-765-8 5-nitro-o-toluidine
2-amino-4-nitrotoluene
7 106-47-8 612-137-00-9 203-401-0 4-chloroaniline
8 615-05-4 612-200-00-0 210-406-1 4-methoxy-m-phenylenediamine
2,4-diaminoanisole 9 101-77-9 612-051-00-1 202-974-4 4,4'-methylenedianiline
4,4'-diaminodiphenylmethane 10 91-94-1 612-068-00-4 202-109-0 3,3'-dichlorobenzidine
3,3'-dichlorobiphenyl-4,4'-ylenediamine 11 119-90-4 612-036-00-X 204-355-4 3,3'-dimethoxybenzidine
o-dianisidine 12 119-93-7 612-041-00-7 204-358-0 3,3'-dimethylbenzidine
4,4'-bi-o-toluidine 13 838-88-0 612-085-00-7 212-658-8 4,4'-methylenedi-o-toluidine
14 120-71-8 612-209-00-X 204-419-1 6-methoxy-m-toluidine
p-cresidine
15 101-14-4 612-078-00-9 202-918-9 4,4'-methylene-bis-(2-chloro-aniline)
2,2'-dichloro-4.4’-methylene-dianiline 16 101-80-4 612-199-00-7 202-977-0 4,4'-oxydianiline 17 139-65-1 612-198-00-1 205-370-9 4,4'-thiodianiline 18 95-53-4 612-091-00-X 202-429-0 o-toluidine
2-aminotoluene
19 95-80-7 612-099-00-3 202-453-1 4-methyl-m-phenylenediamine
2,4-toluylendiamine 2,4-diaminotoluene 20 137-17-7 612-197-00-6 205-282-0 2,4,5-trimethylaniline 21 90-04-0 612-035-00-4 201-963-1 o-anisidine
2-methoxyaniline 22b
60-09-3 611-008-00-4 200-453-6 4-aminoazobenzene
a The CAS-numbers 97-56-3 (No. 5) and 99-55-8 (No. 6) are further reduced to CAS-numbers 95-53-4 (No. 18) and
95-80-7 (No. 19).
b
Azo colorants that are able to form 4-aminoazobenzene, generate under the condition of this method aniline (CAS-number 62-53-3) and 1,4-phenylenediamine (CAS – number 106-50-3). Due to detection limits, only aniline may be detected. The presence of these colorants should be tested by EN 14362-3.
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