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Innovative new chemistry has begun delivering environmentally sound processes, that use energy and raw materials more efficiently. Recent advances in catalysis, for example, permit chemical reactions to e run at lower temperatures and pressures. This change, in turn, reduces the energy demands of the processes and simplifies the selection of construction materials for the processing facility. Novel catalysts are also being uses to avoid the production of unwanted by-products. ¸ïÐµĻ¯Ñ§·½·¨ÒÑ¿ªÊ¼Éè¼Æ¶Ô»·¾³ºÏÀíµÄ¹¤ÒÕ¹ý³Ì£¬ÒÔ±ã¸üΪÓÐЧµÄʹÓÃÄÜÁ¿ºÍÔ­²ÄÁÏ¡£ÀýÈ磬´ß»¯¼Á·½ÃæµÄ½üÆÚ½øÕ¹Ê¹»¯Ñ§·´Ó¦¿ÉÒÔÔڽϵ͵ÄζȺÍѹÁ¦Ï½øÐС£·´¹ýÀ´£¬ÕâÖָıäÓÖ¼õÉÙÁËÕâЩ¹ý³ÌµÄÄÜÁ¿ÐèÇ󣬼ò»¯ÁËÖÆÔì¼Ó¹¤É豸¶Ô¹¹³É²ÄÁϵÄÑ¡Ôñ£¬ÐµĴ߻¯¼Á»¹ÓÃÓÚ±ÜÃâÉú²ú²»Ï£ÍûµÄ¸±²úÆ·¡£

4. Control of Power Plant Emissions

Coal-, oil-, and natural-gas-fired power generation facilities contribute to the emissions of carbon monoxide, hydrocarbons, nitrogen oxides, and a variety of other undesired by-products such as dust and traces of mercury. A rapidly increasing array of technologies are now available to reduce the emissions of unwanted species to meet national or local standards. Chemists and chemical engineers have made major contributions to the state of the art, and catalytic science is playing a critical role in defining the leading edge. 4. ·¢µç³§ÅÅ·ÅÎïµÄ¿ØÖÆ

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The simultaneous control of more than one pollutant is the aim of some recently developed catalyst or sorbent technologies. For example, catalytic methods allow carbon monoxide to be oxidized at the same time that nitrogen oxides are being chemically reduced in gas turbine exhaust. Other research efforts are aimed at pilot-plant evaluation of the simultaneous removal of sulfur and nitrogen oxides from flue gas by the action of a single sorbent and without the generation of massive volumes of waste products.

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5. Environmentally Friendly Products

Increased understanding of the fate of products in the environment had led scientists to design ¨Dgreener¡¬ products. A significant early example comes from the detergent industry in the 1940s and 1950s, new products were introduced that were based on synthetic surfactants called branched alkylbenzene sulfonates. These detergents had higher cleaning efficiency, but it was subsequently discovered that their presence in waste water caused foaming in streams and rivers. The problem was traced to the branched alkylbenzene sulfonates; unlike the soaps used previously, these were

not sufficiently biodegraded by the microbes in conventional sewage treatment plants. An extensive research effort to understand the appropriate biochemical processes permitted chemists to design and synthesize another new class of surfactants, linear alkylbenzene sulfonateas,. The similarity in molecular structure between these new compounds and the natural fatty acids of traditional soaps allowed the microorganisms to degrade the new formulations, and the similarity to the branched alkybenzene sulfonates afforded outstanding detergent performance. 5£® ¶Ô»·¾³ÓÑÉÆµÄ²úÆ·

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Novel biochemistry is also helping farmers reduce the use of insecticides. Cotton plants, for example, are being genetically modified to make them resistant to the cotton bollworm. A single gene from a naturally occurring bacterium, when transferred into cotton plants, prompts the plant to produce a protein that is ordinarily produced by the bacterium. When the bollworm begins to eat the plant, the protein kills the ins4ct by interrupting its digestive processes.

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6. Recycling

Increasing problems associated with waste disposal have combined with the recognition that some raw material exist in limited supply to dramatically increase interest in recycling. Recycling of metals and most paper is technically straightforward, and these materials are now commonly recycled in many areas around the world. Recycling of plastics presents greater technical challenges. Even after they are separated from other types of waste, different plastic materials must be separated from each other. Even then, the different chemical properties of the various types of plastic will require the development of a variety of recycling processes. 6. ´¦Àí

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Some plastics can be recycled by simply melting and molding them or by dissolving them in an appropriate solvent and then reformulating them into a new plastic material. Other materials require more complex treatment, such as breaking down large polymer molecules into smaller

subunits that can subsequently be used as building blocks for new polymers. Indeed, a major program to recycle plastic soft drink bottles by this route is now in use.

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A great deal of research by chemists and chemical engineers will be needed to successfully develop the needed recycling technologies. In some cases, it will be necessary to develop entirely new polymers with molecular structures that are more amenable to the recycling process.

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7. Separation and Conversion for Waste Reduction

New processes are needed to separate waste components requiring special disposal from those that can be recycled or disposed of by normal means. Development of these processes will require extensive research to obtain a fundamental understanding of the chemical phenomena involved. 7. ͨ¹ý·ÖÀëºÍת»»¼õÉÙ·ÏÎïÁ¿

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Metal-bearing spent acid waste. Several industrial processes produce acidic waste solutions in large quantities. Could this waste be separated into clean water, reusable acid, and a sludge from which the metals could be recovered? Such processes would preserve the environment, and their costs could be competitive with disposal costs and penalties.

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Industrial waste treatment. The hazardous organic components in industrial wastewater could be destroyed with thermocatalytic or photocatalytic processes. A promising line of research employs ¨Dsupercritical¡¬ water at high temperatures and pressures. Under these conditions, water exhibits very different chemical and physical properties. It dissolves reactions of many materials that are nearly inert under normal conditions. ¹¤Òµ·ÏË®´¦Àí¡£¹¤Òµ·ÏË®ÖеÄÓк¦ÓлúÎïÄܱ»ÈÈ´ß»¯»ò¹â´ß»¯µÄ¹ý³ÌÆÆ»µ¡£Ò»Ïîǰ¾°ºÜºÃµÄÑо¿¹¤×÷ÊÇÀûÓøßθßѹϵij¬ÁÙ½çË®¡£ÔÚÕâÖÖÌõ¼þÏ£¬Ë®±íÏÖ³ö½ØÈ»²»Í¬µÄÎïÀíºÍ»¯Ñ§ÐÔÖÊ£¬Ëü¿ÉÒÔÈܽⲢÓÐÖúÓÚÄÇЩÔÚ³£Ì¬ÏµÄË®Öм¸ºõÊǶèÐÔµÄÎïÖÊ·¢Éú·´Ó¦¡£

High-level nuclear waste. Substantial savings would be achieved if the volume and complexity of nuclear waste requiring storage could be significantly reduced; this reduction would require economic separation of the radioactive components from the large volumes of other materials that accompany the nuclear waste. The hazardous chemical waste mighty then be disposed of separately. The dispose of nuclear waste will require major research and development efforts over many years.

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Membrane technology. Separations involving semi permeable membranes offer considerable promise. These membranes, usually sheets of polymers, are impervious to some kinds of chemicals but not to others. Such membranes are used to purify water, leaving behind dissolved salts and providing clean drinking water. Membrane separations are also applicable to gases and are being used for the recovery of minor components in natural gas, to enhance the heating value of natural gas by removal of carbon dioxide, and for the recovery of nitrogen from air. Research challenges include the development of membranes that are chemically and physically more resilient, that are less expensive to manufacture, and that provide better separation efficiencies to reduce processing costs.

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Biotechnology. Scientists have turned to nature for help in destroying toxic substances. Some microorganisms in soil, water, and sediments can adapt their diets to a wide variety of organic chemicals; they have been used for decades in conventional waste treatment systems. Researchers are now attempting t coax even higher levels of performance from these gifted microbes by carefully determining the optimal physical, chemical, and nutritional conditions for their existence. Their efforts may lead to the design and operation of a new generation of biological waste treatment facilities. A major advance in recent years is the immobilization of such microorganisms in bioreactors, anchoring them in a reactor while they degrade waste materials. Immobilization permits high flow rates that would flush out conventional reactors, and the use of new, highly porous support materials allows a significant increase in the number of microorganisms for each reactor.

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Excel in Your Engineering

When I reflect on my 20-plus years of experience as a chemical engineer, I realize how wonderful my profession is. As engineers, we provide the essential link between technology and humanity. Our job is to make the world better for its human inhabitants while protecting the environment. And we fulfill our mission amongst the demands and guidelines of the business world.

But sometimes we get so bogged down in the everyday aspects of our jobs that we lose sight of the big picture. We forget to appreciate engineering¡ªthough it is challenging, creative, interesting, significant, and even fun.

For example, there¡®s nothing like getting engrossed in a tough technical problem and coming up with a neat solution. Do you find yourself hurrying to the office because you look forward to working? Do you ever wake up in the middle of the night thinking about a problem and lie there working out the details of a brilliant solution? Do you get up to write notes so you won¡®t forget your breakthrough in the morning?

Engineering can be that wonderful. And being involved in your work doesn¡®t mean you¡®re a nut or a workaholic. We should like what we do: Enjoying something and doing it well is a ¨Dchicken-and-egg¡¬ situation. We tend to like activities we perform well, and to be good at things we enjoy. So here¡®s some advice for both enjoying and improving your engineering work. 1. Enhance technical skills

Engineering provides many opportunities to develop existing skills and to learn new ones. In fact, we have to keep learning or we atrophy--that¡®s the nature of any profession. The ability to grow is one reward of a good job. As your interests and involvements change, and as technology changes, you need to keep learning.


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