试题标准答案
一.单项选择题
1A 2D 3D 4B 5D 6C 7A 8D 9A 10E 11B 12C 13A 14C 15A
二、判断题：
1√ 2 х 3√ 4х 5√ 6х 7√ 8√ 9х 10√ 三、填充题：
1.Lewis-Randall定则， Henry定则 2．dU=TdS－PdV;3.0， 0, ?R dH =TdS + VdP; dA =－PdV－SdT; dG =VdP－SdT
?xlnx RT?xlnx
iiii
四、简答题： 五、计算题： 1、
V?Vl?1?x??Vgxx?V?Vl1000?1.0121??0.0803Vg?Vl12032?1.0121H?Hl?1?x??Hgx?209.33?0.91697?2592.2?0.08303?407.18Jg?1S?Sl?1?x??Sgx
?0.7038?0.91697?8.0763?0.08303?1.3159Jg?1K?1G?H?TS?407.18?323.15?1.3159??18.053Jg?1
2、V1= 28-20X1+10 X1 2 V2= 40 + 10 X1 2
V1?= 28 cm3 /mol V2?= 50 cm3 /mol V1 = 18 cm3 /mol V2 = 40 cm3 /mol ΔV = 10X1 X2
E
V = 10X1 X2
6
3.
GE22??(xiln?i)?x1Ax2?x2Ax1?Ax1x2RT?f2ln?1?ln(1 )?Ax2x1f1??Ax2?lnx?lnf?Ax2?lnx?A?B?Clnf121121?f2ln?2?ln(2 )?Ax1x2f2??Ax2?lnx?lnf?Ax2?lnx?Alnf212112??ff21lnf?x1ln?x2ln1?A?Bx1?Cx1x1x2?Ax1x2?(B?C)x1?A 7