annex A.
Every page of an SDS shall include the name of the chemical product as used on the label. and shall be dated and numbered. The page numbering system should include the total number of pages or should indicate the last page as such. The date indicated shall be the latest revision date.
The 16 sections shall be separated clearly. The headings and subheadings shall be presented in a conspicuous way.
Texts in an SDS should be written in a clear and concise manner. Commonly used phrases are recommended. An SDS should be in a language acceptable to the recipient
Annex A (normative)
Instructions for the compilation and completion of an SDS
The following instructions are intended as guidance for the compilation and completion of SDSs. Their purpose is to ensure that the content of each of the sections listed will enable recipients to take the necessary measures relating to safety, protection of health at the workplace and protection of the environment.
-The 16 sections of SDSs shall be completed in accordance with the recommendations and requirements of this annex.
-This annex lists the main items which will be used to complete the 16 sections. This annex lists the main items only, because it is impracticable to list all items which may possibly be included in an SDS.
-These main items may be used as subheadings in an SDS. If they are used, the
wording given is recommended, not obligatory. The preferred wording is
underlined. Other items may be used as subheadings, but are not recommended.
-Information not specifically relevant to one of the items/subheadings mentioned in this annex, but relevant for the SDS,may be stated under an
additional subheading,called for instance \
-For a given chemical product, not all of the items/subheadings listed have to be used and completed, since some of them are optional.
-Items/subheadings shall be included in the SDS in accordance with the following criteria:
Standard: the notation [S] associated with an item/subheading indicates that the accurate data or information shall be supplied in every case and for every product, thus providing complete information. Statements such as \, \
2、MSDS ISO11014-1 标准(接上贴)
Informative: the notation[ I] associated with an item/subheading indicates that explicit information shall be given, even though the corresponding items are not relevant to the product concerned or the information is not available yet. Statements such as %used, if they can be justified, Professional judgement should be used in selecting these statements.
Applicable: the notation[ A] associated with an item/subheading indicates that
both the items and the data listed may be relevant to.
-the product concerned (properties, use, etc.); -Local requirements;
-safety, prevention and protection.
Subheadings marked [A] for which no information is available shall be deleted. -In no case,[S].[I]or [A],are subheadings without relevant information allowed. 1 PRODUCT AND COMPANY IDENTIFICATION
This section shall state the product name as used on the lable[S] icode [A] ,as well as the name [S] ,address [S]and telephone number [S] of the supplier. If applicable, the emergency telephone number[ A] used by the company should be given. Telex number[ A] and telefax number [A] may also be given.
2 COMPOSITION/INFORMATION ON INGREDIENTS
This section shall state whether the chemical product is a substance or a preparation [S].
In the case of a substance, the common chemical name or the generic name [S] shall be given. Synonyms [A] , if any, and the Chemical Abstract Service Registry Number (CAS number)[A] should be given. Ingredients contributing to the hazard [I] shall also be indicated.
In the case of a preparation, information about the chemical nature [I] of the product shall be given. It is not necessary to give the full composition. When defined, components contributing to the hazard [ I] or impurities contributing to the hazard [A] of the preparation should be given, With their chemical or generic
name [I]and their concentration or concentration range [I].The classification and hazard labelling[A] of these components or impurities may be given.
Reference should be made to the classification system used. 3 HAZARDS IDENTIFICATION
This section shall clearly and briefly summarize the most important hazards and effects of the product [I](adverse human health effects[A],environmental effects [A],physical and chemical hazards [A]and, where appropriate, specific hazards [I].
Main symptoms [A] can be given as well.
The classification [A] of the chemical product may be given. Reference should be made to the classification system used.
An \4 FIRST-AID MEASURES
This section shall state the first-aid measures to be taken, if necessary. If appropriate, it shall state which actions have to be avoided at all costs. The information should be readily understandable by the victim and/or the first-aider.
The information [S] shall be subdivided according to the different exposure routes, i.e. inhalation [A] skin contact [A],eye contact [A] and ingestion[A].
A brief description [A] of the most important symptoms and effects may be given here, but a detailed description of symptoms and effects should be given under heading 11.
If appropriate, advice for the protection of first-aiders[A] and/or special notes
to a physician [A] may be included here.
5 FIRE-FIGHTING MEASURES
This section shall state which extinguishing media are suitable [I]and subsequently, if appropriate, which extinguishing media are NOT suitable [A].
Specific hazards [A] with regard to fire-fighting measures, specific methods [A] of fire-fighting and special equipment for the protection of firefighters [A] should be indicated here.
6 ACCIDENTAL RELEASE MEASURES This section shall contain information on: -Personal precautions [I]; -environmental precautions [I];
-methods for cleaning up [S] (recovery [A]neutralization [A]and disposal, if different from section 13 [A]).
This information should include prevention of secondary hazards [A]. 7 HANDLING AND STORAGE Handling [I]
This subsection shall describe appropriate technical measures [I]( prevention of user exposure [A],prevention of fire and explosion [A]) and precautions [I] for safe handling of the chemical product, such as local and general ventilation and measures to prevent aerosol and dust generation. It shall contain specific safe handling advice [I], such as avoidance of contact with incompatible materials.
Storage [I]